Data · dataset · 2026
Raw Data for "A Crystalline Ylide-Stabilized Stibenium Cation"
Listed in TUDOdata
PROJECT DESCRIPTION: With increasing interest in heavier carbene analogs and the expanding field of ylides as stabilizing substituents in main-group chemistry, we report the synthesis of the first ylide-stabilized stibenium cation 3.
Description
Despite the high electron-donating capabilities of ylide substituents, increased stabilization by sulfur handles attached to the backbone of the ylide substituents, confirmed by computational studies proved to be the key to successfully synthesizing a stable stibenium cation.
Furthermore, a Sb-based lone pair is present in the HOMO, which is contradictory to previous reports on isolable stibenium cations, further showcasing the exotic nature of ylide-substituents in main-group chemistry. DATASET DESCRIPTION: Single folders were created for all isolated compounds. Within those folders, subfolders for each experiment types (NMR, IR, CHN, Reaction-NMR) were created with the related data within those folders.
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The names of the raw-data folders are in accordance with the electronic-laboratory-journal (ELN) used in the Gessner-group, with additional descriptive information, which compound and/or which reaction is contained in that folder. Programs that can be used to open the data: CHN: PDF with the measurement data were provided. IR: The data can be opened with OMNIC software (an open source alternative would be the software "OpenChrom").
NMR: Can be opened with MestReNova XYZ: Can be opened with standard text editors OUT: Can be opened with standard text editors
Links
Where it is published
- Dataverse dataset page data.tu-dortmund.de/dataset.xhtml?persistentId=doi%3A10.17877%2FRESOLV-2026-ML1510… ↗
landing page · from data tu dortmund de
- DOI doi.org/10.17877/resolv-2026-ml1510mu ↗
DOI / persistent id · from data tu dortmund de
Catalogue records · 1
- Dataverse API data.tu-dortmund.de/api/datasets/:persistentId/?persistentId=doi%3A10.17877%2FRESO… ↗
metadata API · from data tu dortmund de
Topics
- Stated by source
- Chemistry
- From keywords
- Chemistry · Engineering · Humanities · Mathematics & Statistics · Social Science
- Inferred from text
- Organic chemistry 70% · Text 75%
Provenance · 1 source records, 14 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| TUDOdata | doi:10.17877/RESOLV-2026-ML1510MU | 11 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| concepts[field].anzsrc:group:3405 | enrichment · data tu dortmund de | taxonomy-embedding@1.0.0 | title+keywords+description (70%) |
| concepts[field].dataverse_subject:chemistry | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| concepts[field].local:field:chemistry | mapping · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| concepts[field].local:field:engineering | mapping · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| concepts[field].local:field:humanities | mapping · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| concepts[field].local:field:mathematics-statistics | mapping · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| concepts[field].local:field:social-science | mapping · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| concepts[modality].local:modality:text | enrichment · data tu dortmund de | keyword-concept-rules@1.0.0 | title+description (75%) |
| created_date | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | |
| description | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /description |
| publication_date | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | |
| title | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /name |
| updated_date | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | |
| version_label | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 |