Data · dataset · 2025
Raw Data for "Palladium-Catalyzed Monoarylation of Cyclopropylamine"
Listed in TUDOdata
PROJECT DESCRIPTION: We report a novel palladium-catalyzed protocol for the monoarylation of cyclopropylamine using the sterically demanding and electron-rich adamantyl-substituted YPhos ligand adYPhos.
Description
This method enables the efficient coupling of a wide range of (hetero)aryl chlorides at room temperature. The reported ligand enhances the scope for the application of YPhos ligands in amination reactions to more challenging substrates.
The protocol is versatile, accommodating various functional groups and extending to larger cycloalkylamines, all accessible under feasible and mild conditions. DATASET DESCRIPTION: Single folders were created for all separate analysis methods. The folders GC-MS (Isolations), HRMS, IR, NMR contain the datasets of the isolated molecules of the project with the respective analysis method.
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They are named with the number of the respective molecule according to the publication and with the number of the experiment of our electronic lab journal. The folder GC-FID (Screening) contains all GC-Data of the reported reaction optimization, following the numbering of the entries in the supporting information. Programs that can be used to open the data: GC: Masshunter Qualitative Analysis (an open source alternative would be the software "OpenChrom").
HRMS: PDF with the measurement data were provided. IR: The data can be opened with OMNIC software (an open source alternative would be the software "OpenChrom"). NMR: Can be opened with MestReNova
Links
Where it is published
- Dataverse dataset page data.tu-dortmund.de/dataset.xhtml?persistentId=doi%3A10.17877%2FRESOLV-2025-MANYIQ… ↗
landing page · from data tu dortmund de
- DOI doi.org/10.17877/resolv-2025-manyiqli ↗
DOI / persistent id · from data tu dortmund de
Catalogue records · 1
- Dataverse API data.tu-dortmund.de/api/datasets/:persistentId/?persistentId=doi%3A10.17877%2FRESO… ↗
metadata API · from data tu dortmund de
Topics
- Stated by source
- Chemistry
- From keywords
- Chemistry · Engineering · Humanities · Mathematics & Statistics · Social Science
- Inferred from text
- Physical chemistry 73%
Provenance · 1 source records, 13 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| TUDOdata | doi:10.17877/RESOLV-2025-MANYIQLI | 10 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| concepts[field].anzsrc:group:3406 | enrichment · data tu dortmund de | taxonomy-embedding@1.0.0 | title+keywords+description (73%) |
| concepts[field].dataverse_subject:chemistry | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| concepts[field].local:field:chemistry | mapping · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| concepts[field].local:field:engineering | mapping · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| concepts[field].local:field:humanities | mapping · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| concepts[field].local:field:mathematics-statistics | mapping · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| concepts[field].local:field:social-science | mapping · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /subjects |
| created_date | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | |
| description | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /description |
| publication_date | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | |
| title | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | /name |
| updated_date | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 | |
| version_label | source · data tu dortmund de | connector:data_tu_dortmund_de@1.0.0 |