Supplementary material from "Effect of wall-mediated hydrodynamic fluctuations on the kinetics of a Brownian nanoparticle"

Phys. 68 , 2959–2970. (doi:10.1063/1.436049)) and the subsequent development of methods such as transition path sampling have laid the foundation for explicitly quantifying the rate process in terms of microscopic simulations.

However, explicit methods to account for how the hydrodynamic correlations impact the transient reaction rate are missing in the colloidal literature. We show that the composite generalized Langevin equation (Yu et al. 2015 Phys. Rev.