Data · dataset · 2023
Synthesis, thermal behavior and energy performance of nitroguanidyl-functionalized energetic materials
Listed in ScienceDB
Six nitroguanidyl-functionalized nitrogen-rich compounds were synthesized and characterized by EA, FT-IR, 1H NMR and 13C NMR.
Description
In addition, the crystal structures of ANPTz, CABNG and FANG were further determined by X-ray single crystal diffractometer. The thermal decomposition behaviours were studied by DSC-TG-FTIR-MS coupling technique and the results showed that all the compounds had good thermal stability, among which ANPTz had the best thermal stability (Td=211.03 ℃).
In addition, HCN, CO2, H2O and NO2 were released during thermal decomposition process. The self-accelerating decomposition temperature (TSADT) and thermal explosion critical temperature (Tb) were calculated to evaluate thermal safety, and the relative order was as follows: FANG (TSADT=198.68 ℃, Tb=209.97 ℃)> ANPTz (TSADT=194.12 ℃, Tb=208.63 ℃)> BANTz (TSADT=182.52 ℃, Tb=207.54 ℃)> AANG (TSADT=180.04 ℃, Tb=188.35 ℃)> CABNG (TSADT=176.80 ℃, Tb=187.32 ℃)> MABNG (TSADT=173.61 ℃, Tb=184.29 ℃).
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The results indicated that FANG had the acceptable sensitivity (IS=7.84 J), good detonation performance (D=8320 m·s-1, P=30.02 GPa), and the significant catalytic effect (the decomposition temperature of RDX decreased by 8.31 ℃).
Links
Where it is published
- DOI doi.org/10.57760/sciencedb.12604 ↗
DOI / persistent id · from scidb cn
Catalogue records · 1
- OAI-PMH record scidb.cn/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=10.57760%2… ↗
metadata API · from scidb cn
Topics
- From keywords
- Earth & Environmental Science · Energy · Engineering · Humanities · Life Sciences · Psychology & Behavioral Science · Social Science
Provenance · 1 source records, 12 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| ScienceDB | 10.57760/sciencedb.12604 | 11 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:earth-environmental | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:energy | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:engineering | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:humanities | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:life-sciences | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:psychology-behavioral | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| concepts[field].local:field:social-science | mapping · scidb cn | connector:scidb_cn@1.0.0 | |
| description | source · scidb cn | connector:scidb_cn@1.0.0 | /metadata/dc/description |
| license | source · scidb cn | connector:scidb_cn@1.0.0 | /metadata/dc/rights |
| publication_date | source · scidb cn | connector:scidb_cn@1.0.0 | |
| title | source · scidb cn | connector:scidb_cn@1.0.0 | /metadata/dc/title |