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Data · dataset · 2026

ICARUS Chamber Experiment: 2014 FIXCIT Study_20140125_METHACROLEIN/hydrogen peroxide_Hydroxyl radical_Ammonium sulfate_Methacrolein + OH, low NO, dry, (NH4)2SO4 seed at end

Listed in National Center for Atmospheric Research

Goals: Study methacrolein low NO chemistry.

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Summary

We successfully oxidized MACR in low NO conditions. About 9 ppb was remaining by the time we turned off lights. After we turned off lights we added in dry ammonium sulfate seed and the AMS saw aerosol uptake.

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The main peaks increasing on the CF3O- CIMS were hydroxyacetone, acetic acid, formic acid, and peroxyacetic acid. Note the night prior to this experiment we cleaned the bag with Milli-Q water, and then flushed the bag overnight at 40 C to dry it. RH was typical in the morning at ~3%.

Organization: 2014 FIXCIT Study Lab Affiliation: California Institute of Technology Chamber: Seinfeld chambers Experiment Category: Gas phase chemical reaction, Aerosol formation Oxidant: Hydroxyl radical Reactants: METHACROLEIN, hydrogen peroxide Reaction Type: Photooxidation Relative Humidity: 5 Temperature: 28 Seed Name: Ammonium sulfate Pressure: 750

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National Center for Atmospheric Research98e183fa-7230-45ff-81ad-c704e304bf6010 d agoJSON v1
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concepts[field].local:field:chemistrymapping · data ucar educonnector:data_ucar_edu@1.0.0
concepts[field].local:field:earth-environmentalmapping · data ucar educonnector:data_ucar_edu@1.0.0
concepts[field].local:field:life-sciencesmapping · data ucar educonnector:data_ucar_edu@1.0.0
concepts[field].local:field:ocean-atmosphericmapping · data ucar educonnector:data_ucar_edu@1.0.0
concepts[field].local:field:social-sciencemapping · data ucar educonnector:data_ucar_edu@1.0.0
created_datesource · data ucar educonnector:data_ucar_edu@1.0.0
descriptionsource · data ucar educonnector:data_ucar_edu@1.0.0/notes
publication_datesource · data ucar educonnector:data_ucar_edu@1.0.0
titlesource · data ucar educonnector:data_ucar_edu@1.0.0/title
updated_datesource · data ucar educonnector:data_ucar_edu@1.0.0