Table · dataset · 2019
Data for Rhodium(III) complexes featuring coordinated CF3 appendages
Listed in figshare
The synthesis and characterisation of a homologous series of rhodium 2,2′‐biphenyl complexes featuring intramolecular dative bonding of the nominally inert and weakly coordinating trifluoromethyl group are described.
Description
Presence of these interactions is evidenced in the solid state using X‐ray diffraction, with Rh−F contacts of 2.36–2.45 Å, and in solution using NMR spectroscopy, through hindered C−CF3 bond rotation and the presence of time‐averaged 1JRhF and 2JPF coupling.<br><br>Rhodium(III) Complexes Featuring Coordinated CF3 Appendages.
The primary analytical data is organised by new rhodium complex. Alphanumeric codes of the form JEK#_### are lab book. references.
Links
Where it is published
- DOI doi.org/10.82444/warw.33778798.v1 ↗
DOI / persistent id · from figshare com
Catalogue records · 1
- OAI-PMH record api.figshare.com/v2/oai?verb=GetRecord&metadataPrefix=oai_dc&identifier=oai%3Af… ↗
metadata API · from figshare com
Topics
- From keywords
- Astronomy & Astrophysics · Chemistry · Computer Science & AI · Earth & Environmental Science · Economics & Finance · Engineering · Humanities · Life Sciences · Medicine & Health · Ocean & Atmospheric Science · Social Science
- Inferred from text
- Macromolecular and materials chemistry 74%
Provenance · 1 source records, 17 field assertions
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|---|---|---|---|
| figshare | oai:figshare.com:article/33778798 | 7 d ago | JSON v1 |
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