Data for Monolayer-to-thin-film transition in supramolecular assemblies: the role of topological protection

The templated 2D structure of TPA can smoothly map to its 3D structure through continuous molecular tilting within the unit cell, whilst the 3D structure of TMA is topologically distinct from its 2D form, so that only an abrupt transition is possible. The concept of topological protection of the 2D structure gives a new tool for the molecular design of nanostructured films.<br><br>These folders include the data used in the images in the main paper.

Further data can be obtained on request from the authors. The data are organised into folders corresponding to each figure, as listed below: Figure 1: •TMA STM image (panel a): tma_graphene.093 •TPA STM image (panel d): tpa_graphene.116 Figure 2: •Diffraction Intensity modulation graph (panel g): Delta_I_Modulation.txt, Delta_I_Modulation_Error.txt, Film_Thickness.txt, Film_Thickness_Error.txt •Diffraction Intensity Profile graph (panel f): Profile_TMA_15s.txt, Profile_TMA_1min.txt, Profile_TMA_6min.txt, Profile_TMA_18min.txt, Relative_Angle.txt •Film Thickness graph (panel e): Deposition_Time.txt, Film_Thickness.txt, Film_Thickness_Error.txt •TEM diffraction patterns (panels a1,b1,c1,d1): TMA_15s_diffraction_pattern.dm3, TMA_1min_diffraction_pattern.dm3, TMA_6min_diffraction_pattern.dm3, TMA_18min_diffraction_pattern.dm3 •TEM low mag images (panels a2,b2,c2,d2): TMA_15s_low_mag_image.dm3, TMA_1min_low_mag_image.dm3, TMA_6min_low_mag_image.dm3, TMA_18min_low_mag_image.dm3 Figure 3: •TMA HRTEM image (panel a): TMA_15s_HRTEM.dm3 Figure 4: •TMA simulation image (panel a): Image_simulation.tiff •TPA reconstruction image (panel b): Reconstruction_Image.png Figure 5: •Diffraction Intensity modulation graph (panel g): Delta_I_Modulation.txt, Delta_I_Modulation_Error.txt, Film_Thickness.txt, Film_Thickness_Error.txt •Diffraction Intensity Profile graph (panel f): Profile_TPA_15s.txt, Profile_TPA_1min.txt, Profile_TPA_6min.txt, Profile_TPA_18min.txt, Relative_Angle.txt •Film Thickness graph (panel e): Deposition_Time.txt, Film_Thickness.txt, Film_Thickness_Error.txt •TEM diffraction patterns (panels a1,b1,c1,d1): TPA_15s_diffraction_pattern.dm3, TPA_1min_diffraction_pattern.dm3, TPA_6min_diffraction_pattern.dm3, TPA_18min_diffraction_pattern.dm3 •TEM low mag images (panels a2,b2,c2,d2): TPA_15s_low_mag_image.dm3, TPA_1min_low_mag_image.dm3, TPA_6min_low_mag_image.dm3, TPA_18min_low_mag_image.dm3