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On the secular trend of COx and CO₂ in the lower thermosphere

Listed in National Center for Atmospheric Research

An analysis of recent observations (2004-2013) made by the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) instrument indicate that total carbon (COx = CO + CO₂) has been increasing rapidly in the lower thermosphere, above 10-3 hPa (90 km).

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The estimated trend (~9% per decade) is about a factor of 2 larger than the rate of increase that can be ascribed to anthropogenic emissions of CO₂ (~5% per decade).

Here we investigate whether the observed trends of CO₂ and COx can be reproduced using the Whole Atmosphere Community Climate Model (WACCM), a comprehensive global model with interactive chemistry, wherein vertical eddy diffusion is estimated from a parameterization of gravity wave breaking that can respond to changes in the model climate. We find that the modeled trends of CO₂ and COx do not differ significantly at any altitude from the value expected from anthropogenic increases of CO₂ and that WACCM does not produce significant changes in eddy diffusivity.

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We show that the discrepancy between model and observations cannot be attributed to uncertainties associated with geophysical noise and instrumental effects, to difficulties separating a linear trend from the 11 year solar signal, or to sparse sampling by ACE-FTS. Estimates of the impact of vertical diffusion on CO₂ in the model indicate that a large increase in Kzz (~30% per decade) would be necessary to reconcile WACCM results with observations.

It might be possible to ascertain whether such a large change in vertical mixing has in fact taken place by examining the trend of water vapor in the upper mesosphere.

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Climate model simulation 65%
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concepts[method].local:method:climate-modelenrichment · data ucar edukeyword-concept-rules@1.0.0title+description (65%)
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descriptionsource · data ucar educonnector:data_ucar_edu@1.0.0/notes
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updated_datesource · data ucar educonnector:data_ucar_edu@1.0.0