Data · collection · 2015

Syntheses, crystal structures, and electrochemistry of novel Fe 2 SN and FeSN carbonyl complexes with pendant bases

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Reactions of Fe 2 (CO) 9 with thioacylhydrazones ArCH=NNHCSPh in THF afford Fe 2 (CO) 6 (μ-κ 2 S:κ 2 N-PhC(S)=NNCHArCHArN(CHAr)N=CSPh) ( 1 , Ar = C 6 H 5 ; 3 , Ar = 4-CH 3 C 6 H 4 ) and Fe(CO) 3 (κ 2 S:N-PhC(=S)NHNCHArCHArN(CHAr)N=CSPh) ( 2 , Ar = C 6 H 5 ; 4 , Ar = 4-CH 3 C 6 H 4 ).