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Data · dataset · 2024

Dataset for the publication: Brown carbon aerosol in rural Germany: sources, chemistry, and diurnal variations

Listed in RADAR and RADAR4Memory — shown once because both records carry DOI 10.35097/d0prpzkxqkq2t09y

Brown carbon aerosol (BrC) is one major contributor to atmospheric air pollution in Europe, especially in winter.

Description

Therefore, we studied the chemical composition, diurnal variation, and sources of BrC from 17th February to 16th March at a rural location in southwest Germany. In total, 178 potential BrC molecules (including 7 nitro aromatic compounds, NACs) were identified in the particle phase comprising on average 63 ± 32 ng m−3, and 31 potential BrC (including 4 NACs) molecules were identified in the gas phase contributing on average 6.2 ± 5.0 ng m−3 during the whole campaign.

The 178 potential BrC molecules only accounted for 2.3 ± 1.5 % of the total organic mass, but can explain 11 ± 11 % of the total BrC absorption at 370 nm, assuming an average mass absorption coefficient at 370 nm (MAC370) of 9.5 m2 g−1. A few BrC molecules dominated the total BrC absorption. In addition, diurnal variations show that gas phase BrC was higher at daytime and lower at night.

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It was mainly controlled by secondary formation (e.g. photooxidation) and particle-to-gas partitioning. Correspondingly, the particle phase BrC was lower at daytime and higher at nighttime. Secondary formation dominates the particle-phase BrC with 61 ± 21 %, while 39 ± 21 % originated from biomass burning.

Furthermore, the particle-phase BrC showed decreasing light absorption due to photochemical aging. This study extends the current understanding of real-time behaviors of brown carbon aerosol in the gas and particle phase at a location characteristic for the central Europe.

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Where it is published

Catalogue records · 1

Topics

Provenance · 2 source records, 9 field assertions
SourceKeyLast seenRaw
RADAR10.35097/d0prpzkxqkq2t09y11 d agoJSON v1
RADAR4Memory10.35097/d0prpzkxqkq2t09y11 d agoJSON v1
FieldAssertionExtractorEvidence
access_levelsource · radar service eu deconnector:radar_service_eu_de@1.0.0
concepts[field].local:field:chemistrymapping · radar4memory radar service euconnector:radar4memory_radar_service_eu@1.0.0
concepts[field].local:field:chemistrymapping · radar service eu deconnector:radar_service_eu_de@1.0.0
concepts[field].local:field:earth-environmentalmapping · radar service eu deconnector:radar_service_eu_de@1.0.0
concepts[field].local:field:earth-environmentalmapping · radar4memory radar service euconnector:radar4memory_radar_service_eu@1.0.0
descriptionsource · radar service eu deconnector:radar_service_eu_de@1.0.0/metadata/dc/description
licensesource · radar service eu deconnector:radar_service_eu_de@1.0.0/metadata/dc/rights
publication_datesource · radar service eu deconnector:radar_service_eu_de@1.0.0
titlesource · radar service eu deconnector:radar_service_eu_de@1.0.0/metadata/dc/title