Replication Data for: H-Tunneling Rotamerization in Glycine Imine

The gas-phase tunneling half-life is 11 h according to the one-dimensional WKB model and 1 h according to the multidimensional CVT/SCT model, both aligning well with our experimental results. This dataset contains experimental data of IR and NMR spectra published in the manuscript "H-Tunneling Rotamerization in Glycine Imine". Spectra labeled as 'Figure...' are presented in the appropriate figures in the main text or the Supporting Information (SI).

Spectra without this caption were used solely for the assignment of different conformers of glycine imine and do not have corresponding figures. All captions, except for NMR and ATR spectra, follow the structure: compound → IR region → matrix host → process. Here, 365, 282, and 254 nm, as well as OPO, indicate photolysis at the respective wavelengths, while 'tunneling' refers to a resulting spectrum recorded after hours in the dark without an IR filter.