Data · dataset · 2026
Data for Confinement-Induced Z-Selectivity in the Rhodium N-Heterocyclic Carbene-Catalyzed Hydroboration of Terminal Alkynes
Listed in DaRUS
The concept of solid catalyst coated with a 1 nm layer of an ionic liquid [BMIM+ BF4-] was employed, resulting in a 22-fold increase in β(Z)-selectivity for Rh(I)- and Rh(III)- complexes based on N- and O-chelating N-heterocyclic carbenes (NHCs).
Description
The primary data files for the synthesized ligand and complexes as well as performed catalysis are provided. The labeling of the data files proceeded according to the corresponding figures in the supporting information.
It includes NMR of the synthesized complexes and catalysis, physisorption measurements and IR measurements. The Crystal data for the complexes Rh3, Rh5 and Rh6 is deposited in the Cambridge Structural Database (CSD) of the Cambridge Crystallographic Data Centre (CCDC).
Links
Where it is published
- Dataverse dataset page darus.uni-stuttgart.de/dataset.xhtml?persistentId=doi%3A10.18419%2FDARUS-5678 ↗
landing page · from darus uni stuttgart de
- DOI doi.org/10.18419/darus-5678 ↗
DOI / persistent id · from darus uni stuttgart de
Catalogue records · 1
- Dataverse API darus.uni-stuttgart.de/api/datasets/:persistentId/?persistentId=doi%3A10.18419%2FDARU… ↗
metadata API · from darus uni stuttgart de
Topics
- Stated by source
- Chemistry
- From keywords
- Chemistry
- Inferred from text
- Organic chemistry 72%
Provenance · 1 source records, 9 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| DaRUS | doi:10.18419/DARUS-5678 | 11 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| concepts[field].anzsrc:group:3405 | enrichment · darus uni stuttgart de | taxonomy-embedding@1.1.0 | title+keywords+description (72%) |
| concepts[field].dataverse_subject:chemistry | source · darus uni stuttgart de | connector:darus_uni_stuttgart_de@1.0.0 | /subjects |
| concepts[field].local:field:chemistry | mapping · darus uni stuttgart de | connector:darus_uni_stuttgart_de@1.0.0 | /subjects |
| created_date | source · darus uni stuttgart de | connector:darus_uni_stuttgart_de@1.0.0 | |
| description | source · darus uni stuttgart de | connector:darus_uni_stuttgart_de@1.0.0 | /description |
| publication_date | source · darus uni stuttgart de | connector:darus_uni_stuttgart_de@1.0.0 | |
| title | source · darus uni stuttgart de | connector:darus_uni_stuttgart_de@1.0.0 | /name |
| updated_date | source · darus uni stuttgart de | connector:darus_uni_stuttgart_de@1.0.0 | |
| version_label | source · darus uni stuttgart de | connector:darus_uni_stuttgart_de@1.0.0 |