Constarium
← Search

Data · collection · 2018

K-axis dissolved iron (dFe) data from the Kerguelen-Axis region of the Southern Ocean

Listed in NASA Earthdata CMR

Sampling was conducted according to GEOTRACES protocols.

Description

Samples for trace element analyses, including dissolved iron (dFe), were filtered through acid-cleaned 0.2 um cartridge filters (Pall Acropak) under constant airflow from several ISO class 5 HEPA units. All plastic ware was acid-cleaned prior to use, following GEOTRACES protocols.

Samples were collected into low-density polyethylene (LDPE) bottles, acidified immediately to pH 1.7 with Seastar Baseline hydrochloric acid (HCl), double-bagged and stored at room temperature until analysis on shore. Samples for dFe analysis were pre-concentrated offline (factor 40) on a SeaFAST S2 pico (ESI, Elemental Scientific, USA) flow injection system with a Nobias Chelate-PA1 column. Samples were eluted from the column in 10% distilled nitric acid (HNO3), with calibration based on the method of standard additions in seawater (made using multi-element standards in a 10% HNO3 matrix, rather than an HCl matrix).

Read the rest (3 more)

Pre-concentrated samples were analysed using Sector Field Inductively Coupled Plasma Mass Spectrometry (SF-ICP-MS, Thermo Fisher Scientific, Inc.). Data were blank-corrected by subtracting an average acidified milli-Q blank that was treated similarly to the samples. The dFe detection limit for a given analysis run on the SeaFAST/SF-ICP-MS was calculated as 3 x standard deviation of the milli-Q blank on that run.

Detection limits ranged from 0.016 to 0.067 nmol kg-1, with a median of 0.026 nmol kg-1 (n=12). GEOTRACES reference materials were analyzed along with samples and results were in good agreement with consensus values: SAFe D1 was measured at 0.69 +/- 0.05 nmol kg-1 (n=7; consensus value = 0.67 +/- 0.04 nmol kg-1) and GD was measured at 1.02 +/- 0.01 nmol kg-1 (n=6; consensus value = 1.00 +/- 0.1 nmol kg-1). Comments regarding the data spreadsheet: NaN = no sample dFe QC flags: 1 = high confidence in data quality 2 = detection limit 3 = low confidence in data quality detection limits: dFe data that were below the daily detection limit were replaced with the respective detection limit.

They are flagged with the number 2 in the dFe QC flag column.

Links

Get the data

Where it is published

Documentation and papers

Catalogue records · 2

Topics

Inferred from text
Mass spectrometry 75%
Provenance · 1 source records, 16 field assertions
SourceKeyLast seenRaw
NASA Earthdata CMRC1625715202-AU_AADC12 d agoJSON v1
FieldAssertionExtractorEvidence
access_levelsource · NASA CMRconnector:nasa_cmr@1.0.0
concepts[instrument].gcmd_instrument:go-flo-bottlessource · NASA CMRconnector:nasa_cmr@1.0.0
concepts[measured_variable].gcmd:earth-science/oceans/ocean-chemistry/nutrientssource · NASA CMRconnector:nasa_cmr@1.0.0
concepts[measured_variable].gcmd:earth-science/oceans/ocean-chemistry/trace-elementssource · NASA CMRconnector:nasa_cmr@1.0.0
concepts[modality].local:modality:mass-spectrometryenrichment · NASA CMRkeyword-concept-rules@1.0.0title+description (75%)
concepts[platform].gcmd_platform:not-providedsource · NASA CMRconnector:nasa_cmr@1.0.0
concepts[platform].gcmd_platform:r-v-aasource · NASA CMRconnector:nasa_cmr@1.0.0
concepts[platform].gcmd_platform:r-v-umsource · NASA CMRconnector:nasa_cmr@1.0.0
concepts[platform].gcmd_platform:shipssource · NASA CMRconnector:nasa_cmr@1.0.0
descriptionsource · NASA CMRconnector:nasa_cmr@1.0.0/umm/Abstract
license_textsource · NASA CMRconnector:nasa_cmr@1.0.0
publication_datesource · NASA CMRconnector:nasa_cmr@1.0.0
spatialsource · NASA CMRconnector:nasa_cmr@1.0.0/umm/SpatialExtent
temporalsource · NASA CMRconnector:nasa_cmr@1.0.0/umm/TemporalExtents
titlesource · NASA CMRconnector:nasa_cmr@1.0.0/umm/EntryTitle
version_labelsource · NASA CMRconnector:nasa_cmr@1.0.0