Data · collection · 2018
K-axis dissolved iron (dFe) data from the Kerguelen-Axis region of the Southern Ocean
Listed in NASA Earthdata CMR
Sampling was conducted according to GEOTRACES protocols.
Description
Samples for trace element analyses, including dissolved iron (dFe), were filtered through acid-cleaned 0.2 um cartridge filters (Pall Acropak) under constant airflow from several ISO class 5 HEPA units. All plastic ware was acid-cleaned prior to use, following GEOTRACES protocols.
Samples were collected into low-density polyethylene (LDPE) bottles, acidified immediately to pH 1.7 with Seastar Baseline hydrochloric acid (HCl), double-bagged and stored at room temperature until analysis on shore. Samples for dFe analysis were pre-concentrated offline (factor 40) on a SeaFAST S2 pico (ESI, Elemental Scientific, USA) flow injection system with a Nobias Chelate-PA1 column. Samples were eluted from the column in 10% distilled nitric acid (HNO3), with calibration based on the method of standard additions in seawater (made using multi-element standards in a 10% HNO3 matrix, rather than an HCl matrix).
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Pre-concentrated samples were analysed using Sector Field Inductively Coupled Plasma Mass Spectrometry (SF-ICP-MS, Thermo Fisher Scientific, Inc.). Data were blank-corrected by subtracting an average acidified milli-Q blank that was treated similarly to the samples. The dFe detection limit for a given analysis run on the SeaFAST/SF-ICP-MS was calculated as 3 x standard deviation of the milli-Q blank on that run.
Detection limits ranged from 0.016 to 0.067 nmol kg-1, with a median of 0.026 nmol kg-1 (n=12). GEOTRACES reference materials were analyzed along with samples and results were in good agreement with consensus values: SAFe D1 was measured at 0.69 +/- 0.05 nmol kg-1 (n=7; consensus value = 0.67 +/- 0.04 nmol kg-1) and GD was measured at 1.02 +/- 0.01 nmol kg-1 (n=6; consensus value = 1.00 +/- 0.1 nmol kg-1). Comments regarding the data spreadsheet: NaN = no sample dFe QC flags: 1 = high confidence in data quality 2 = detection limit 3 = low confidence in data quality detection limits: dFe data that were below the daily detection limit were replaced with the respective detection limit.
They are flagged with the number 2 in the dFe QC flag column.
Links
Get the data
- Download the data data.aad.gov.au/eds/4595/download ↗
download · from NASA CMR
Where it is published
- DOI doi.org/10.4225/15/5a77d6bd5975e ↗
DOI / persistent id · from NASA CMR
Documentation and papers
- data.aad.gov.au /aadc/metadata/citation.cfm?entry_id=AAS_4344_dFe ↗
Citation reference for this metadata record and dataset.
documentation · from NASA CMR
- Public information for AAS project AAS_4344 secure3.aad.gov.au/proms/public/projects/report_project_public.cfm?project_no=AAS… ↗
project · from NASA CMR
Catalogue records · 2
- CMR UMM-JSON cmr.earthdata.nasa.gov/search/concepts/C1625715202-AU_AADC.umm_json ↗
metadata API · from NASA CMR
- CMR record cmr.earthdata.nasa.gov/search/concepts/C1625715202-AU_AADC.html ↗
catalogue entry · from NASA CMR
Topics
- Stated by source
- GO-FLO BOTTLES · Not provided · Nutrients · R/V Aurora Australis · R/V UMITAKA MARU · SHIPS · Trace Elements
- Inferred from text
- Mass spectrometry 75%
Provenance · 1 source records, 16 field assertions
| Source | Key | Last seen | Raw |
|---|---|---|---|
| NASA Earthdata CMR | C1625715202-AU_AADC | 12 d ago | JSON v1 |
| Field | Assertion | Extractor | Evidence |
|---|---|---|---|
| access_level | source · NASA CMR | connector:nasa_cmr@1.0.0 | |
| concepts[instrument].gcmd_instrument:go-flo-bottles | source · NASA CMR | connector:nasa_cmr@1.0.0 | |
| concepts[measured_variable].gcmd:earth-science/oceans/ocean-chemistry/nutrients | source · NASA CMR | connector:nasa_cmr@1.0.0 | |
| concepts[measured_variable].gcmd:earth-science/oceans/ocean-chemistry/trace-elements | source · NASA CMR | connector:nasa_cmr@1.0.0 | |
| concepts[modality].local:modality:mass-spectrometry | enrichment · NASA CMR | keyword-concept-rules@1.0.0 | title+description (75%) |
| concepts[platform].gcmd_platform:not-provided | source · NASA CMR | connector:nasa_cmr@1.0.0 | |
| concepts[platform].gcmd_platform:r-v-aa | source · NASA CMR | connector:nasa_cmr@1.0.0 | |
| concepts[platform].gcmd_platform:r-v-um | source · NASA CMR | connector:nasa_cmr@1.0.0 | |
| concepts[platform].gcmd_platform:ships | source · NASA CMR | connector:nasa_cmr@1.0.0 | |
| description | source · NASA CMR | connector:nasa_cmr@1.0.0 | /umm/Abstract |
| license_text | source · NASA CMR | connector:nasa_cmr@1.0.0 | |
| publication_date | source · NASA CMR | connector:nasa_cmr@1.0.0 | |
| spatial | source · NASA CMR | connector:nasa_cmr@1.0.0 | /umm/SpatialExtent |
| temporal | source · NASA CMR | connector:nasa_cmr@1.0.0 | /umm/TemporalExtents |
| title | source · NASA CMR | connector:nasa_cmr@1.0.0 | /umm/EntryTitle |
| version_label | source · NASA CMR | connector:nasa_cmr@1.0.0 |